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The major organic compound formed by the reaction of 1,1,1-trichloroethane with silver powder is

  • acetylene

  • ethene

  • 2-butyne

  • 2-butyne


C.

2-butyne

 The reaction is 

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The order of stability of the following carbocations,

  • III>II>I

  • II> III>I

  • I>II>III

  • I>II>III


D.

I>II>III

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An unknown alcohol is treated with the “Lucas reagent” to determine whether the alcohol is primary, secondary or tertiary. Which alcohol reacts fastest and by what mechanism

  • Secondary alcohol by SN1

  • Tertiary alcohol by SN1

  • Secondary alcohol by SN2

  • Secondary alcohol by SN2


B.

Tertiary alcohol by SN1

Reaction proceeds through carbocation formation as 30 carbocation is highly stable, hence reaction proceeds through SN1 with 30 alcohol. 

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What is DDT among the following

  • Greenhouse gas 

  • A fertilizer

  • Biodegradable pollutant

  • Biodegradable pollutant


D.

Biodegradable pollutant

DDT is P,P' - Dichlorodiphenyl trichloro ethane. It was used as an insecticide. DDT is not metabolised very rapidly by animals. It was also discovered to have a high toxicity towards fish. Therefore, It is a non-bio degradable pollutant.

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2–Hexyne gives trans–2–Hexene on treatment with

  • Pt/H2

  • Li/NH3

  • Pd/BaSO4

  • Pd/BaSO4


B.

Li/NH3



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