Subject

Chemistry

Class

JEE Class 12

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 Multiple Choice QuestionsMultiple Choice Questions

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11.

The dissociation constant of acetic acid Ka is 1.74 × 10-5 at 298 K. The pH of a solution of 0.1 M acetic acid is :

  • 2.88

  • 3.6

  • 4.0

  • 1.0


A.

2.88

For 0.1 M acetic acid or C = 0.1 mL-1

Ka = 1.74 × 10-5

pH = ?

According to Ostwald dilution formula,

[H+] = Ka × c

       = 1.7 × 10-5 × 0.1

       = 0.017 × 10-4

pH = -log10 [H+]

    = -log10 0.017 × 10-4

    = 2.88

The pH of a solution of 0.1M acetic acid is 2.88.


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12.

0.365g of HCl gas was passed through 100 cm3 of 0.2 M NaOH solution. The pH of the resulting solution would be :

  • 13

  • 9

  • 8

  • 5


13.

In the given reaction,

2X (g) + Y (g)  2Z (g) + 80 kcal

Which combination of pressure and temperature will give the highest yield of Z at equilibrium?

  • 1000 atm and 200°C

  • 500 atm and 500°C

  • 1000 atm and 100°C

  • 500 atm and 100°C


14.

The presence of Ag+ ion increases the solubility of alkenes due to the formation of :

  • dπ-dσ bonding

  • pσ-pπ bonding

  • pπ- bonding

  • None of the above


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15.

Which of the following compounds would have the smallest value for pKa?

  • CHF2CH2CH2COOH

  • CH3CH2CF2COOH

  • CH2FCHFCH2COOH

  • CH3CF2CH2COOH


16.

Commercial 11.2 volume H2O2 solution has a molarity of :

  • 1.0

  • 0.5

  • 11.2

  • 1.12


17.

Which one of the following oxides is amphoteric ?

  • ZnO

  • MgO

  • CaO

  • CO2


18.

Each B - H - B bridge in B2H6 is formed by the sharing of:

  • 2 electrons

  • 4 electrons

  • 1 electron

  • 3 electrons


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19.

Which carbon is more electronegative ?

  • sp3 - hybridised carbon

  • sp - hybridised carbon

  • sp2 - hybridised carbon

  • Always same irrespective of its hybrid state


20.

In Lassaigne's test, a blue colour is obtained if the organic compound contains nitrogen. The blue colour is due to

  • K4[Fe(CN)6]

  • Fe4[Fe(CN)6]3

  • Na3[Fe(CN)6]

  • Cu2[Fe(CN)6]


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