Subject

Chemistry

Class

JEE Class 12

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 Multiple Choice QuestionsMultiple Choice Questions

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11.

The correct order of ionization energies is

  • Cu > Ag > Au

  • Cu > Au > Ag

  • Au > Cu > Ag

  • Ag > Au > Cu


C.

Au > Cu > Ag

On moving down in a group, valence shell become for away from the nucleus and thus nucleus attraction towards test electron decreases which results in decrease in ionisation energy. So, the correct order should be Cu > Ag > Au.


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12.

Among the following compounds both coloured and paramagnetic one is

  • K2Cr2O7

  • VOSO4

  • (NH4)2.[TiCl2]

  • K3[Cu(CN)4]


13.

Which of the following has maximum bond energy?

  • C=C

  • C=O

  • O=O

  • N=O


14.

An organic compound crystallises in an ortho rhombic system with two molecules per unit cell. The unit cell dimensions are 12.05, 15.05 and 2.69 Å. If the density of the crystal is 1.419 g cm-3, then molar mass of compound will be 

  • 207 g mol-1

  • 209 g mol-1

  • 308 g mol-1

  • 317 g mol-1


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15.

The molarity of a solution in which 5.3 g Na2CO3 is dissolved in 500 mL will be

  • 1.0 M

  • 0.1 M

  • 0.20 M

  • 0.2 M


16.

1 mL of 0.01 N HCl is added to 999 mL solution of 0.1 N Na2SO4. The pH of the resulting solution will

  • 2

  • 7

  • 5

  • 1


17.

The equilibrium constants for the reaction,

Br2  2Br → 1

at 500 K and 700 K are 1 × 10-10 and 1 × 10-5 respectively. The reaction is

  • endothermic

  • exothermic

  • fast

  • slow


18.

A chemist wishes to prepare a buffer solution of pH = 2.90 that efficiently resists a change in pH yet contains only small concentration of buffering agents which one of the following weak acid along with its salt would be best to use 

  • m-chlorobenzoic acid (pKa = 3.98)

  • Acetoacetic acid (pKa = 3.58)

  • 2 5-dihydrobenzoic acid (pKa = 2.97)

  • p-chlorocmanic acid (pKa = 4.41)


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19.

If 5 L of H2O2 produces 50 L of O2 at NTP, H2O2 is

  • 50 volume

  • 10 volume

  • 5 volume

  • None of the above


20.

The wave number of hydrogen atom in Lyman series is 82200 cm-1. The electron goes from

  • n3 → n2

  • n2 → n1

  • n4 → n3

  • None of these


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