Subject

Chemistry

Class

JEE Class 12

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 Multiple Choice QuestionsMultiple Choice Questions

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11.

In which of the following, homolytic bond fission takes place?

  • Free radical chlorination of methane

  • Addition of HBr to double bond

  • Alkaline hydrolysis of ethyl chloride

  • Nitration of benzene


A.

Free radical chlorination of methane

Free radical chlorinaton of methane.

Initiation

(1) Cl2 light 2Cl°   Propagation(2) Cl + CH4 HCl + CH3(3) CH3 + Cl2  CH3Cl + Cl°Termination(4) 2Cl°  Cl2Cl+ CH3  CH3Cl 2CH3CH3CH3


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12.

Which of the following metallic oxide exhibit amphoteric nature?

  • CaO

  • Al2O3

  • Na2O

  • BaO


13.

Pick the correct statement among the following statement.

  • Sodium dodecyl benzene sulphonate used in tooth paste ts a cationic detergent

  • Non-ionic detergents is formed when polyethylene glycol reacts with adipic acid

  • Cetyl trimethyl ammonium bromide is a popular cationic detergent used in air conditioner

  • Sodium lauryl sulphate forms an insoluble scum with hard water


14.

3ClO-(aq) → ClO- + 2Cl is an example of

  • Oxidation reaction

  • reduction reaction

  • disproportionation reaction

  • decomposition reaction


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15.

In the manufacture of hydrogen from water gas (CO + H2), which of the following is correct statement?

  • CO and H2 are separated based on difference in their densities

  • H2 is removed by occlusion with Pd

  • CO is oxidised to CO2 with steam in the presence of a catalyst followed by absorption of CO2 alkali

  • Hydrogen is isolated by diffusion


16.

Plaster of Paris is represented as

  • CaSO4·2H2O

  • CaSO4

  • CaSO4·H2O

  • CaSO4·12H2O


17.

Square planar complex of the type MAXBL (where A, B,X and L) are unidenate ligands) shows following set of isomers.

  • two cis and one trans

  • two trans and one cis

  • two cis and two trans

  • three cis and one trans


18.

By passing electric current, NaClO3 is converted in to NaClO4 according to the following equation

NaClO3 + H2O → NaClO4 + H2

How many moles of NaClO4 will be formed when three Faradays of charges is passed through NaClO3 ?

  • 3.0

  • 1.5

  • 0.75

  • 1.0


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19.

The pressure of real gases is less than that of ideal gas because of

  • increases in the kinetic energy of the molecules

  • increases in the number of collisions

  • intermolecular attraction

  • finite size of particles


20.

In a face centred cubic arrangement of A and B atoms in which 'A' atoms are at the corners of the unit cell and 'B atoms are at the face centres. One of the 'A' atoms is missing from one corner in unit cell.The simplest formula of compounds is

  • A7B8

  • A7B3

  • AB3

  • A7B24


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