Arrange the following compounds in order of increasing boiling

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 Multiple Choice QuestionsShort Answer Type

61.

Arrange the following compounds in increasing order of their acid strength.
Propan-1-ol, 2, 4, 6-trinitrophenol, 3-nitro-phenol, 3, 5-dinitrophenol, phenol, 4-methyl phenol.

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62.

Why has tertiary alcohol higher reactivity towards hydrogen halide compared to secondary and primary alcohols?

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63.

State what happens when isopropyl chloride is boiled with alcoholic potassium hydroxide solution.

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64.

Give reason: nitration of phenol gives ortho and para products only.

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65.

Which electrophile is the attacking reagent when phenol and chloroform undergoes Reimer Tiemann reaction?

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66.

Write the equation for the industrial synthesis of methanol.

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67.

Write the structure of the major product and also label the product as 1°, 2° or 3° alcohol.

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68.

Name the enzymes which convert sucrose into glucose and fructose and finally into ethanol.

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69. What is the expected product from the reaction of



with
(i) LiAlH4,    (ii) H2/Pt?
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70.

Arrange the following compounds in order of increasing boiling points:
Penta-1-ol, butan-1-ol, butan-2-ol, ethanol, propan-1-ol, methanol.


Boiling point of alcohol increase with increase in the
number of carbon atoms (increase in van der Waals forces). Thus, order of increasing boiling point,

Methanol < ethanol < propan-1 -ol < butan-2-ol < butan-1-ol < pentan-1-ol.
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