Discuss the Relative reactivity of alcohols towards Lucas reage

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 Multiple Choice QuestionsLong Answer Type

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391. Discuss the Relative reactivity of alcohols towards Lucas reagent.


Primary alcohols on reaction with Lucas reagents (Conc. HCl/anhy.ZnCl2) does not forms white cloudiness or turbidity at room temperature.

RCH2OH + Lucas Regent -->No Reaction

Secondary alcohol : Secondary alcohol on reaction with locals reagent (Conc. HCl/anhy.ZnCl2) forms white cloudiness or turbidity appears with in about 5 minutes.

R2CHOH+ Lucas reagent --> R2CHCl


Tertiary alcohol: Tertiary alcohol on reaction with Lucas Reagent (Conc. HCl/anhy.ZnCl2) forms white cloudiness or turbidity immediately.

R3C-OH +lucas --> R3CCl

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