Out of the compounds below the vapour pressure of (B) at a partic

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651.

Out of the compounds below the vapour pressure of (B) at a particular temperature is

                     

  • higher than that of (A)

  • lower than that of (A)

  • higher or lower than (A), depending on the size of the vessel

  • same as that of (A)


A.

higher than that of (A)

In (A) para-nitro phenol intermolecular (between two molecules) H-bonding exists while in (B) ortho- nitro phenol, intramolecular H-bonding exists. Because of the presence of intramolecular H-bonding, 'the boiling point of (B) is lower as compared to (A) and thus, (B) is more volatile, ie, has higher vapour pressure as compared to (A).


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652.

An oxygen containing organic compound upon oxidation forms a carboxylic acid as the only organic product with its molecular mass higher by 14 units. The organic compound is

  • an aldehyde

  • a primary alcohol

  • a secondary alcohol

  • a ketone


653.

Phenol X forms a tribromo derivative, 'X' is

  • bromine in benzene

  • bromine in water

  • potassium bromide solution

  • bromine in carbon tetrachloride at 0°C


654.

The compound which gives turbidity immediately with Lucas reagent at room temperature is

  • butan-1-ol

  • butan-2-ol

  • 2-methyl propan-2-ol

  • 2-methyl propan-1-ol


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655.

The conversion of m-nitrophenol to resorcinol involves respectively

  • hydrolysis, diazotization and reduction 

  • diazotization, reduction and hydrolysis

  • hydrolysis, reduction and diazotization

  • reduction, diazotization and hydrolysis


656.

HCHO was treated with a reagent X. The product formed upon hydrolysis in the presence of an acid gave C2H5OH. The reagent X is

  • alcoholic KOH

  • alcoholic KCN

  • CH3MgI

  • aqueous KOH


657.

Which one of the following is not formed when a mixture of methyl bromide and bromobenzene is heated with sodium metal in the presence of dry ether?

  • diphenyl

  • propane

  • toulene

  • ethane


658.

Power alcohol is a mixture of

  • 80% petrol + 20% ethanol + small quantity of benzene

  • 80% ethanol + 20% benzene + small quantity of petrol

  • 50% Petrol + 50% ethanol + small quantity of benzene

  • 80% petrol + 20% benzene + small quantity of ethanol


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659.

Identify 'C' in the following

  • ethanol

  • propanone

  • cumene hydroperoxide

  • water


660.

Which of the following is strongly acidic?

  • Phenol

  • o-cresol

  • p-nitrophenol

  • p-cresol


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