Phenol on treatment with diethyl sulphate in presence of NaOH giv

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 Multiple Choice QuestionsMultiple Choice Questions

691.

Toluene on treatment with CrOand (CH3CO)2O followed by hydrolysis with dil HCl gives

  • benzaldehyde

  • benzoic acid

  • phenol

  • phenylacetaldehyde


692.

Diacidic base is

  • CH2(OH)2

  • Ca(OH)2

  • CH3CH(OH)2

  • All of these


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693.

Phenol on treatment with diethyl sulphate in presence of NaOH give

  • phenetole

  • anisole

  • diphenyl ether

  • diethyl ether


A.

phenetole

Phenol on alkylation gives phenoliv ether. Since, diethyl sulphate in the presence of NaOH acts as alkylating agent, it causes alkylation of phenol to give ethyl phenyl ether which is also called phenetole.

C2H5OH + NaOH C2H5O-Na+ + H2OC2H5O-Na+ + (C2H5)2SO4diethyl sulphate  C6H5OC2H5phentole + C2H5NaSO4


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694.

The step which never be involved in the dehydration of alcohol is

  • protonation

  • elimination

  • hydride transfer

  • carbanion formation


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695.

The boiling point of ethanol is higher as compared to the boiling point of diethyl ether though both have the same molecular formula. This is due to

  • resonance

  • -R group

  • H-bonding

  • covalent bonding


696.

Which one of the following compounds will not react with CH3MgBr ?

  • Ethyl acetate

  • Acetone

  • Dimethyl ether 

  • Ethanol


697.

Dehydration of alcohol usually goes by

  • E1 mechanism

  • E2 mechanism

  • E1 cb mechanism

  • SN2 mechanism


698.

Phenol reacts with dilute nitric acid at normal temperature to form

  • o-nitrophenol

  • m-nitrophenol

  • o-and p-nitropheno

  • 2, 4, 6-trinitrophenol


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699.

Which of the following compounds does not give Friedel-Craft's reaction ?

  • benzene

  • xylene

  • nitrobenzene

  • phenol


700.

Which one is the correct IUPAC name of the following compound?

   

  • 1-chloro-5-hydroxycydohexane

  • 2-chloro-4-hydroxycyclohexane

  • 3-chloro-3-cyclohexenol

  • 5-hydroxycydohexenyl chloride


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