Assertion : Sucrose is a non-reducing sugar.Reason : It has glyco

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 Multiple Choice QuestionsMultiple Choice Questions

1071.

Among the following, the one which reacts most readily with ethanol is

  • p-nitrobenzyl bromide

  • p-chlorobenzyl bromide

  • p-methoxybenzyl bromide

  • p-methylbenzyl bromide.


1072.

The nucleic acid base having two possible binding sites is

  • thymine

  • cytosine

  • guanine

  • adenine.


1073.

o-Toluic acid on reaction with Br2+ Fe gives


1074.

The most suitable reagent for the conversion of

RCH2OH  RCHO is

  • KMnO4

  • K2Cr2O7

  • CrO3

  • PCC (pyridine chloro chromate).


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1075.

Assertion : Sucrose is a non-reducing sugar.

Reason : It has glycosidic linkage.

  • If both assertion and reason are true and reason is the correct explanation of assertion

  • If both assertion and reason are true but reason is not the correct explanation of assertion

  • If assertion is true but reason is false

  • If both assertion and reason are false


A.

If both assertion and reason are true and reason is the correct explanation of assertion

Sucrose is a non-reducing sugar as it does not reduce Tollen's or Fehling's reagent, due to absence of free aldehyde or ketone group. It contains stable acetal or ketal structure which cannot be opened into a free carbonyl group. Sugar is composed of α-D-glucopyranose unit and β-D-fructofuranose unit. These units are joined by α-β-glycosiclic linkage between C-1 of the glucose unit and C-2 of the fructose unit.

 


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1076.

Assertion : lsobutanal does not give iodofonn test.

Reason : It does not have α-hydrogen.

  • If both assertion and reason are true and reason is the correct explanation of assertion

  • If both assertion and reason are true and reason is the correct explanation of assertion

  • If assertion is true but reason is false

  • If both assertion and reason are false.


1077.

In the following reaction order, B is

CH3CH2-COOH P/Br2 A H+alc.KOH B

  • CH2 =CH -COOH

  • CH2-CH(Br)-COOH

  • CH3CH2COBr

  • CH3CH2OH


1078.

The product of the given reaction is-


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1079.

Assertion : CH3OCH3 and C2H5OH has comparable molecular weight but boiling point of C2H5OH is more than dimethyl ether.

Reason : C2H5OH forms intermolecular Hbonding while CH3OCH3 forms intramolecular H-bonding.

  • If both Assertion and Reason are true and Reason is the correct explanation of Assertion.

  • If both Assertion and Reason are true but Reason is not the correct explanation of Assertion.

  • If Assertion is true but Reason is false.

  • If Assertion is false but Reason is true.


1080.

Upon treatment with I2 and aqueous NaOH, which of the following compounds will form iodoform?

  • CH3CH2CH2CH2CHO

  • CH3CH2COCH2CH3

  • CH3CH2CH2CH2CH2OH

  • CH3CH2CH2CH(OH)CH3


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