Assertion : lsobutanal does not give iodofonn test.Reason : It do

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 Multiple Choice QuestionsMultiple Choice Questions

1071.

Among the following, the one which reacts most readily with ethanol is

  • p-nitrobenzyl bromide

  • p-chlorobenzyl bromide

  • p-methoxybenzyl bromide

  • p-methylbenzyl bromide.


1072.

The nucleic acid base having two possible binding sites is

  • thymine

  • cytosine

  • guanine

  • adenine.


1073.

o-Toluic acid on reaction with Br2+ Fe gives


1074.

The most suitable reagent for the conversion of

RCH2OH  RCHO is

  • KMnO4

  • K2Cr2O7

  • CrO3

  • PCC (pyridine chloro chromate).


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1075.

Assertion : Sucrose is a non-reducing sugar.

Reason : It has glycosidic linkage.

  • If both assertion and reason are true and reason is the correct explanation of assertion

  • If both assertion and reason are true but reason is not the correct explanation of assertion

  • If assertion is true but reason is false

  • If both assertion and reason are false


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1076.

Assertion : lsobutanal does not give iodofonn test.

Reason : It does not have α-hydrogen.

  • If both assertion and reason are true and reason is the correct explanation of assertion

  • If both assertion and reason are true and reason is the correct explanation of assertion

  • If assertion is true but reason is false

  • If both assertion and reason are false.


C.

If assertion is true but reason is false

C2H6(CH3)-CHO (Isobutanal has alpha-hydrogen atom). Acetaldehyde, acetone and methyl ketones having CH3CO group undergo haloform reaction. The hydrogen atoms ofthe methyl group are first replaced by halogen atoms. This reaction is used as a test of CH3CO- group. Due to absence of CH3CO- group isobutanal does not give iodoform test.


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1077.

In the following reaction order, B is

CH3CH2-COOH P/Br2 A H+alc.KOH B

  • CH2 =CH -COOH

  • CH2-CH(Br)-COOH

  • CH3CH2COBr

  • CH3CH2OH


1078.

The product of the given reaction is-


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1079.

Assertion : CH3OCH3 and C2H5OH has comparable molecular weight but boiling point of C2H5OH is more than dimethyl ether.

Reason : C2H5OH forms intermolecular Hbonding while CH3OCH3 forms intramolecular H-bonding.

  • If both Assertion and Reason are true and Reason is the correct explanation of Assertion.

  • If both Assertion and Reason are true but Reason is not the correct explanation of Assertion.

  • If Assertion is true but Reason is false.

  • If Assertion is false but Reason is true.


1080.

Upon treatment with I2 and aqueous NaOH, which of the following compounds will form iodoform?

  • CH3CH2CH2CH2CHO

  • CH3CH2COCH2CH3

  • CH3CH2CH2CH2CH2OH

  • CH3CH2CH2CH(OH)CH3


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