Why is the bond angle in PH3 molecule lesser than that in NH

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 Multiple Choice QuestionsShort Answer Type

521. Write the balanced equation for complete hydrolysis of XeF6.
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522. Predict the shape of ClF3 on the basis of VSEPR theory.
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523. In which one of the two structures, NO2 and NO2, the bond angle has a higher value?
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524. Which is a stronger acid in aqueous solutions, HF or HCl?
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525. Why is the bond angle in PH3 molecule lesser than that in NH3 molecule?


The bond pair in NH3 is close to N in N–H bond than the bond pair in P–H bond in PH3. This is because the size of the nitrogen is small than phosphorus. As a result, the force of repulsion between the bonded pair of electrons in PH3 is more than in NH3. Therefore, the bond angle in PH3 molecule is lesser than that in NH3molecule.
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526. Why does the reactivity of nitrogen differ from phosphorus?
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527. Why does NH3 form hydrogen bond but PH3 does not? 
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528. How is nitrogen prepared in the laboratory? Write the chemical equations of the reactions involved.  
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529. How is ammonia manufactured industrially? 
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530. Illustrate how copper metal can give different products with HNO3.
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