Explain the following:(i) Most of the known noble gas compounds a

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 Multiple Choice QuestionsShort Answer Type

701.

How would you account for the following:
Interhalogen compounds are strong oxidising agents.

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702.

How would you account for the following:
Sulphur hexafluoride is less reactive than sulphur tetrafluoride.

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703.

How would you account for the following:
In the noble gases only xenon forms known chemical compounds.

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704. Compare the structural shapes of the following species: SF6 and SF4.
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705.

Write balanced chemical equations for the following reactions:
(a)     Ca3P2+H2O   
(b)     XeF6+3H2O 

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 Multiple Choice QuestionsLong Answer Type

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706. Explain the following:
(i) Most of the known noble gas compounds are those of Xenon.
(ii) ClF3exists but FCl3 does not.
(iii) Among the hydrides of elements of Group 16, water shows unusual physical
properties.
(iv) Unlike phosphorus, nitrogen shows little tendency for catenation.
(v) Despite lower electron affinity, fluorine is a stronger oxidising agent than chlorine.


i) Only xenon is form compound in noble gas because energy level of the 5p orbital, 6s and 4f orbitals are very close and hence energetically accessible.
Only a small amount of energy is needed to excite the pair of electron form the 5p orbital to the 65 and 4f electrons where they can then form covalent bonds with other atom.

ii) The electronic configuration of chlorine atom 1s2 2s2 3s2 3p6 3d0 it has vacant d orbitals it, therefore, can expand it valence shell and show +3 oxidation state, Hence ClF3 is formed.
On other hand, flourine atom 1s2 2s2 2p5 has no d - orbital and, therefore, it can not expand its valence shell. It only shows -1 oxidation state. Hence, FCl3 does not exist.

iii) The oxygen has high electronegativity. Hence the O-H bond in H2O forms strong intermolecular hydrogen bonds. As a result, water exist as an associated molecule. But the other hydrides of group 16 do not form hydrogen bonds. Therefore they exist as discrete molecules. Thus, water shows unusual physical properties such as high thermal stability, high b.p., weaker acidic character as compared to the other hydrides of group 16.


iv) Nitrogen is small in size and have unique ability to form multiple bondingsingleN–N bond is weaker than the single P–P bond because of highinterelectronic repulsion of the non-bonding electrons, owing to the small bond length. As a result the catenation tendency is weaker in nitrogen.

v) Halogens have high electronegativity and electron affinity. They have greater tendency to accept electrons or easily reduced, therefore they are strong oxidizing agent.

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707. Discuss the properties of oxygen, sulphur, selenium, tellurium and polonium (group 16 elements) with reference of following: (i) metallic (non-metallic character), (ii) catenation, (iii) thermal stability of hydrides, (iv) oxidation states (v) allotropy.
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708.

Describe the molecular shapes of the following: (i) SF4, (ii) BrF5, (iii) IF3, (iv) PF5, (v) XeF2.

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709. Give reasons for:
(i) Ozone is more reactive than oxygen.
(ii) An acidified K2Cr2O7 paper on being exposed to SO2 turns green.
(iii) Sulphuric acid never acts as a reducing agent.
(iv) Noble gases are mostly chemically inert.
(v) Nitrogen is fairly inert.
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710. Describe the following about halogen family (group 17 elements):
(i)    Relative oxidising power.
(ii)    Relative acidic strength of their hydrides.
(iii)    Oxyacids and their relative oxidising ability.
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