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 Multiple Choice QuestionsMultiple Choice Questions

251.

The compressibility factor of an ideal gas is :

  • 1

  • 2

  • 4

  • 0


252.

Dalton's law of partial pressure is not applicable to

  • O2+ O3

  • CO + CO2

  • NH3+ HCl

  • I +O2


253.

Positive deviation from ideal behaviour takes place because of

  • molecular interaction between atom and PVnRT>1

  • molecular interaction between atom and PVnRT<1

  • finite size of atoms and PVnRT>1

  • finite size of atoms and PVnRT<1


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254.

The vapour pressure will be lowest for :

  • 0.1 M sugar solution

  • 0.1 M KCl solution

  • 0.1 M Cu(NO3)2 solution

  • 0.1 M AgNO3 solution


C.

0.1 M Cu(NO3)2 solution

Vapour pressure of a solvent is lowered by the presence of solute in it. Lowering in vapour pressure is a colligative property i.e., it depends on the number of particles present in the solution.

Cu(NO3)2 give the maximum number of ions (i.e., 3) so it causes the greatest lowering in vapour pressure of water.


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255.

A gas at 350 K and 15 bar has molar volume 20 percent smaller than that for an ideal gas under the same conditions. The correct option about the gas and its compressibility factor (Z) is :

  • Z > 1 and repulsive forces are dominant

  • Z < 1 and attractive forces are dominant

  • Z < 1 and repulsive forces are dominant

  • Z > 1 and attractive forces are dominant


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