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31.

The molecule having zero dipole moment is

  • CH2Cl2

  • BF3

  • NF3

  • ClF3


B.

BF3

The dipole moment of BF3 molecule is zero due to its symmetrical (triangular planar) structure. The three fluorine atoms lie at the corners of an equilateral triangle with boron at the centre. Thus, the vectorial addition of the dipole moments of the three bonds gives a netsum of zero.


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32.

Which of the following shell, form an outer octahedral complex?

  • d4

  • d8

  • d6

  • None of these


33.

The calculated bond order in O2- ions is

  • 1

  • 1.5

  • 2

  • 2.5


34.

The correct order of decreasing dipole moment of (I) toluene, (II) m-dichlorobenzene (III) o-dichlorobenzene and (IV) p-dichlorobenzene is

  • IV < II < I < III

  • IV < I < II < III

  • I < IV < II < III

  • IV < I < III < II


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35.

Among the following compounds of boron, the species which also forms π-bond in addition to σ-bonds is

  • BH3

  • B2H6

  • BF3

  • BF4-


36.

How many bonds are there in

  • 18σ, 8π

  • 19σ, 4π

  • 14σ, 2π

  • 14σ, 8π


37.

Match the following

List I List II
(a) PCl3 (i) Square planar
(b) BF3 (ii) T-shape
(c) ClF3 (iii) Trigonal pyramidal
(d) XeF4 (iv) See- saw
  (v) Trigaonal planar

  • (a)    (b)  (c)  (d)
    (iv)   (ii)   (i)    (iii)

  • (a)    (b)   (c)    (d)
    (iii)   (v)   (ii)    (iv)

  • (a)  (b)    (c)   (d)
    (iii)   (v)   (ii)   (i)

  • (a)   (b)   (c)    (d)
    (iii)   (v)   (ii)   (v)


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