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 Multiple Choice QuestionsMultiple Choice Questions

31.

The molecule having zero dipole moment is

  • CH2Cl2

  • BF3

  • NF3

  • ClF3


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32.

Which of the following shell, form an outer octahedral complex?

  • d4

  • d8

  • d6

  • None of these


D.

None of these

d4: Forms outer complex in high spin and forms inner complex in low spin. If cannot form octahedral complex.

d: In low spin it forms inner octahedral complex and in high spin forms outer octahedral complex.

d: forms only outer spin octahedral complex.


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33.

The calculated bond order in O2- ions is

  • 1

  • 1.5

  • 2

  • 2.5


34.

The correct order of decreasing dipole moment of (I) toluene, (II) m-dichlorobenzene (III) o-dichlorobenzene and (IV) p-dichlorobenzene is

  • IV < II < I < III

  • IV < I < II < III

  • I < IV < II < III

  • IV < I < III < II


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35.

Among the following compounds of boron, the species which also forms π-bond in addition to σ-bonds is

  • BH3

  • B2H6

  • BF3

  • BF4-


36.

How many bonds are there in

  • 18σ, 8π

  • 19σ, 4π

  • 14σ, 2π

  • 14σ, 8π


37.

Match the following

List I List II
(a) PCl3 (i) Square planar
(b) BF3 (ii) T-shape
(c) ClF3 (iii) Trigonal pyramidal
(d) XeF4 (iv) See- saw
  (v) Trigaonal planar

  • (a)    (b)  (c)  (d)
    (iv)   (ii)   (i)    (iii)

  • (a)    (b)   (c)    (d)
    (iii)   (v)   (ii)    (iv)

  • (a)  (b)    (c)   (d)
    (iii)   (v)   (ii)   (i)

  • (a)   (b)   (c)    (d)
    (iii)   (v)   (ii)   (v)


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