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35.

Assertion : Staggered conformation of ethane is 12.5 kJ mol-1 more stable than the eclipsed conformation.

Reason : The two conformations of ethane cannot be separated at room temperature.

  • If both assertion and reason are true and reason is the correct explanation of assertion

  • If both assertion and reason are true but reason is not the correct explanation of assertion

  • If assertion is true but reason is false

  • If both assertion and reason are false.


B.

If both assertion and reason are true but reason is not the correct explanation of assertion

Staggered conformation is more stable because in this conformation any two hydrogen atoms on adjacent carbon atoms are as far apart as possible and the repulsion between the electron clouds of σ- bonds of two non-bonded hydrogen atoms is minimum.

The energy difference of 12.55 kJ mol-1 is not large enough to prevent rotation at room temperature as a result it is not possible to seperate the two conformations of ethane.


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36.

The C-H bond energy in ethane , ethene and ethyne :

  • more in ethene

  • more in ethane

  • more in ethyne

  • same in all these


37.

The IUPAC name of the given compound is (CH3)3CCH2C(CH3)3

  • 2, 3,4,4-tetramethylpentane

  • 1, 2, 2, 4-tetramethylpentene

  • 2,2,4, 4-tetramethylpentane

  • 3, 3-dimethylpentane.


38.

What is 'A.' in the following reaction?


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39.

Assertion: Saturated hydrocarbons are chemically less reactive.

Reason : All isomeric paraffins have same parent name.

  • If both assertion and reason are true and reason is the correct explanation of assertion.

  • If both assertion and reason are true but reason is not the correct explanation of assertion.

  • If assertion is true but reason is false.

  • If both assertion and reason are false.


40.

Assertion: Chloroform is stored in dark coloured bottles.

Reason: Chronic chloroform exposure may cause damage to liver and kidneys.

  • If both assertion and reason are true and reason is the correct explanation of assertion.

  • If both assertion and reason are true but reason is not the correct explanation of assertion.

  • If assertion is true but reason is false.

  • If both assertion and reason are false.


41.

Assertion : Saturated hydrocarbons are chemically less reactive.

Reason: All isomeric paraftins have same parent name.

  • If both assertion and reason are true and reason is the correct explanation of assertion.

  • If both assertion and reason are true but reason is not the correct explanation of assertion.

  • If assertion is true but reason is false.

  • If both assertion and reason are false.


42.

The end product in the sequence would be 

C3H7OH 170°H2SO4 A Br2 B KOHAlc. C

  • CH3-CCH

  • CH3-C(OH)=CH2

  • CH2=C=CH2

  • CH3-CH(OH)-CH2(OH)


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43.

Assertion: Ortho and para-nitrophenol can be separated by steam distillation.

Reason: Para-nitrophenol is steam volatile due to intramolecular hydrogen bonding.

  • If both assertion and reason are true and reason is the correct explanation of assertion.

  • If both assertion and reason are true but reason is not the correct explanation of assertion.

  • If assertion is true but reason is false.

  • If both assertion and reason are false.


44.

The function of anhydrous AlCl3 in the Friedel-Craft's reaction is to :

  • absorb water

  • absorb HCl

  • to produce electrophile

  • to produce nucleophile


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