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 Multiple Choice QuestionsMultiple Choice Questions

61.

Which of the following has maximum value of flocculating power ?

  • Pb2+

  • Pb4+

  • Sr2+

  • Na+


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62.

Which mixture of the solutions will lead to the formation of negatively charged colloidal [Agl]l– sol ?

  • 50 mL of 1 M AgNO3 + 50 mL of 2 M KI

  • 50 mL of 2 M AgNO3 + 50 mL of 1.5 M KI

  • 50 mL of 0.1M M AgNO3 + 50 mL of 0.1 M KI

  • 50 mL of 1 M AgNO3 + 50 mL of 1.5 M KI


A.

50 mL of 1 M AgNO3 + 50 mL of 2 M KI

Generally charge present on the colloid is due to adsorption of common ion from dispersion medium. Millimole of KI is maximum in option (2) (50 × 2 = 100) so act as solvent and anion I is adsorbed by the colloid AgI formed

AgNO3 + KI       AgI                 +    KNO3D.P         D.M (excess)     Negative chargedcolloid


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