Subject

Chemistry

Class

ICSE Class 12

Pre Boards

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Sample Papers

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 Multiple Choice QuestionsShort Answer Type

11.

Correct the following statements: 

Chloroacetic acid is more acidic than acetic acid because of the - M effect.

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12.

Correct the following statements: 

When acetone is treated with bleaching powder, acetaldehyde is obtained.

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13. The molecular weights of sodium chloride and glucose are determined by the Depression of freezing point method. Compared to their theoretical molecular weights, what will be their observed molecular weights when determined by the above method ? Justify your answer.
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14. An aqueous solution containing 1.70 g of cane sugar in 100 ml water begins to freeze at – 0.093°C. The cryoscopic constant (molal depression constant) of water is 1.86 K Kg mole– 1. Calculate the molecular weight of cane sugar.
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15. A decinormal solution of sodium chloride exerts an osmotic pressure of 4.82 atmosphere at 27°C. Calculate the degree of dissociation of sodium chloride.
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16. The half life of a radioactive isotope is 10 hours. How many atoms of this isotope will be left after 4 hours if initially 1 gm mole of the radioactive isotope was taken ?  
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17. 90Th234 emits 7alpha particles and 6 beta particles. What will be the atomic number and mass number of the resulting atom.
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18. What is the function of the moderator and the control rod in nuclear reactor ? 
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19.  The melting point of pure silver and pure lead is 961°C and 327°C respectively. A molten mixture of the two metals on cooling at a constant temperature forms a eutectic mixture with a composition of approximately 5% silver and 95% lead at 305°C. Draw a schematic phase diagram for the silver-lead system. Label all the parts of the diagram. Indicate the number of components, phases and degrees of freedom present at the eutectic point.
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20. An aqueous solution of an organic compound contains 10 g of solute per litre. When 1 litre of this solution is treated with 100 ml of ether, 6 g of the organic solute is extracted. How much of the solute will be extracted from the aqueous solution by adding further 100 ml of ether ? (Assume that the molecular state of the solute is the same in ether and water.)


Concentration space in space aqueous space layer space straight C subscript 1 space equals space 10 space straight g divided by straight l
space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space 10 divided by 1000 space straight g divided by ml
Concentration space in space organic space layer space straight C subscript 2 space equals space 6 divided by 100 space straight g divided by space ml

Distribution space co minus efficient space straight K subscript straight D space equals space straight C subscript 1 over straight C subscript 2 space equals space fraction numerator 10 divided by 1000 over denominator 6 divided by 100 end fraction space equals space 0.166

amount space organic space compound space space left space in space aqueous space layer space after space first space extraction space space equals space 10 minus 6 space equals space 4 space straight g
Let space straight x space gm space be space the space amount space of space organic space compound space which space is space extracted space in space second space extraction
straight K subscript straight D space equals fraction numerator 4 divided by 1000 over denominator straight x divided by 100 end fraction
0.166 space equals space 4 over 1000 space straight x space 100 over straight x
0.166 space equals space fraction numerator 4 over denominator 10 straight x end fraction
straight x space equals space fraction numerator 4 over denominator 0.166 space straight x space 10 end fraction space equals space 2.40 space straight g space
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