Subject

Chemistry

Class

JEE Class 12

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 Multiple Choice QuestionsMultiple Choice Questions

41.

Tertiary alcohols (3°) having atleast four carbon atoms upon drastic oxidation yield carboxylic acid with

  • one carbon atom less

  • two carbon atoms less

  • three carbon atoms less

  • All the above three options are correct.


42.

Lactic acid molecule has

  • one chiral carbon atom

  • two carbon atoms less

  • three carbon atoms less

  • asymmetric molecule


43.

Which of the following aldehydes give red precipitate with Fehling solution?

  • Benzaldehyde

  • Salicylaldehyde

  • Acetaldehyde

  • None of the above


44.

Aniline reacts with acetaldehyde to form

  • Schiffs base

  • carbylamine

  • immine

  • none of these


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45.

Best method of preparing alkyl chloride is

  • ROH + SOCl2 → 

  • ROH + PCl5 → 

  • ROH + PCl3 →

  • ROH + HCl AnhyZnCl2


46.

Acetylene can be obtained by the reaction

  • HCOOK Electrolysis

  • CHI3 + Ag 

  • CH3CH2OH 443KConc. H2SO4

  • Be2C + H2O →


47.

Which of the following is used in vulcanization of rubber?

  • SF6

  • CF4

  • Cl2F2

  • C2F2


48.

Glucose on oxidation gives the acid containing the C-chiral atoms equal to

  • 2

  • 3

  • 4

  • 5


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49.

A HCl (CH3)2C=CHCOCH3, A is

  • acetone

  • propionaldehyde

  • formaldehyde

  • acetaldehyde


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50.

Formation of alkane by the action of zinc on alkyl halide is called

  • Wurtz reaction

  • Kolbe's reaction

  • Ulmann's reaction

  • Frankland reaction


D.

Frankland reaction

(i) Wurtz reaction2RX + 2Na Ether R-R alkane (ii) Kolbe's reaction RCOONa + H2O Electrolysis  R-Ralkane (iii) Ulmann's reaction 2C6H5I + 2Cu  C6H5-C6H5biphenyl(iv) Frankland reaction2RX + Znalky halide   R-Ralkane 


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