Subject

Chemistry

Class

JEE Class 12

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 Multiple Choice QuestionsMultiple Choice Questions

1.

Which of the following can be represented by the configuration [Kr] 5s2?

  • Ca

  • Sr

  • Ba

  • Ra


2.

2p orbitals have

  • n = 1; l = 2

  • n = 1; l = 0

  • n = 2; l = 1

  • n = 2; l = 0


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3.

Aufbau principle is not satisfied by

  • Cr and Cl

  • Cu and Ag

  • Cr and Mg

  • Cu and Na


B.

Cu and Ag

The electrons presents in the different orbitals of the same subshell can exchange their positions. Each such exchange results in release of energy, called exchange energy and hence, leads to a greater stability. As the number of exchanges that can take place is maximum in the exactly half filled and completely filled arrangements, therefore, exchange energy is maximum and hence, the stability is maximum. 

29Cu - 1s2, 2s2 2p6, 3s2 3p6, 4s1, 3d10

47Ag - 1s2, 2s2 2p6, 3s2 3p6, 4s2, 3d10, 4p6 5s1, 4d10

but Aufbau principle states that electrons are filled in increasing order of energy, hence 4s orbital must be filled first than 3d orbital.

In Cu and Ag both electron first enters in the orbital of lower energy, therefore they does not satisfy Aufbau principle.


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4.

Neutrons are found in atoms of all elements except in

  • chlorine

  • oxygen

  • argon

  • hydrogen


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5.

The atomic weight of an element is 39. The number of neutrons in its nucleus is one more than the number of protons. The number of protons, neutrons and electrons-respectively in its atoms would be

  • 19, 20, 19

  • 19, 19, 20

  • 20, 19, 19

  • 20, 19, 20


6.

Out of the following electronic configurations the one of a transition element, is

  • 1s2, 2s2 2p6, 3s2 3p6 3d10, 4s2 4p6

  • 1s2, 2s2p6, 3s2 3p6 3d3, 4s2

  • 1s2, 2s2 2p6, 3s2 3p6, 4s2

  • 1s2, 2s2 2p6, 3s2 3p6 3d10, 4s2 4p1


7.

A covalent bond between two atoms is formed by which of the following?

  • Electron nuclear attraction

  • Electron sharing

  • Electron transfer

  • Electrostatic attraction


8.

Hybridisation involves

  • addition of an electron pair

  • mixing up of atomic orbitals

  • removal of an electron pair

  • separation of orbitals


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9.

On the basis of Molecular Orbital Theory (MOT) which molecule does not exist?

  • H2

  • He2+

  • He2

  • Li2


10.

Which of the following compounds in liquid state does not have hydrogen bonding?

  • H2O

  • HF

  • NH3

  • C6H6


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