Subject

Chemistry

Class

JEE Class 12

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 Multiple Choice QuestionsMultiple Choice Questions

31.

In a hydrogen-oxygen fuel cell, combustion of hydrogen occurs to

  • generate heat

  • create potential difference between the two electrodes

  • produce high purity water

  • remove adsorbed oxygen from electrode surfaces


32.

Amongst the following compounds, the optically active alkane having lowest molecular mass is

  • CH3-CH2-CH2-CH3

  • CH3-CH2-CH(CH3)-CH3

  • CH3-CH2-C≡CH


33.

Which of the following will have a meso-isomer also?

  • 2-chlorobutane

  • 2,3-dichlorobutane

  • 2,3-dichloropentane

  • 2-hydroxypropanoic acid


34.

The smog is essentially caused by the presence of

  • O2 and O3

  • O2 and N2

  • oxides of sulphur and nitrogen

  • O3 and N2


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35.

In this reaction

CH3CHO + HCN → CH3CH(OH)CN H.OH CH3CH(OH)COOH

an asymmetric centre is generated. The acid obtained would be

  • 50% D + 50% L-isomer

  • 20% D + 80% L-isomer

  • D-isomer

  • L-isomer


36.

Which one of the following octahedral complexes will not show geometrical isomerism? (A and B are monodentate ligands)

  • [MA4B2]

  • [MA5B]

  • [MA2B4]

  • [MA3B3]


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37.

According to IUPAC nomenclature sodium nitroprusside is named as

  • sodium pentacyanonitrosyl ferrate (II)

  • sodium pentacyanonitrosyl ferrate (III)

  • sodium nitroferricyanide

  • sodium nitroferrocyanide


B.

sodium pentacyanonitrosyl ferrate (III)

IUPAC name of sodium niroprusside Na2[Fe(CN)5NO] is sodium pentacyanonitrosoyl ferrate (III) because in it NO is neutral ligand and the oxidation number of Fe is III, which is calculated as-

Let oxidation number of Fe be x.

2 × O.N of Na + x + 5 × O.N. of CN + 1 × O.N of NO = 0

2 × (+1) + x + 5 × (-1) + 1 × 0 = 0

x = 5 - 2 = 3


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38.

Which of the following is responsible for depletion of the ozone layer in the upper strata of the atmosphere ?

  • Polyhalogens

  • Ferrocenes

  • Fullerenes

  • Freons


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39.

CaC2 + N2 → A, product A is

  • CaCN2

  • CaCN2 and C

  • CaCN2 + N2

  • None of these


40.

How many unit cells are present in a cube shaped ideal crystal of NaCl of mass 1.00 gm? [Atomic masses : Na = 23; Cl = 35.5]

  • 2.57 × 1021

  • 5.14 × 1021

  • 1.28 × 1021

  • 1.71 × 1021


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