Which of the following is strongest base? from Chemistry JEE Yea

Subject

Chemistry

Class

JEE Class 12

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 Multiple Choice QuestionsMultiple Choice Questions

41.

Correct order of electron affinities of halogens is

  • F> Cl> Br> I

  • I> Br> Cl> F

  • Cl> F>I>Br

  • Cl>F>Br>I


42.

Atomic radii of Ti, Zr and Hf vary

  • Ti>Zr> Hf

  • Ti<Zr< Hf

  • Ti< Hf<Zr

  • Ti<Zr=HF


43.

If NO2(N2O4) is dissolved in NaOH, we get solution of

  • NaNO2

  • NaNO3

  • mixture of NaNOand NaNO3

  • NaNO4


44.

Correct acidic order of the following compounds is

                        

  • i > ii> iii

  • iii> i> ii

  • ii> iii> i

  • i> iii> ii


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45.

Which of the following is strongest base?

  • C6H5NH2

  • p-NO2-C6H4NH2

  • m-NO2-C6H4NH2

  • C6H5CH2NH2


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46.

Which of the following is strongest base?

  • Perkin's reaction

  • Knoevenagel reaction

  • Reformatsky reaction

  • Benzoin condensation


A.

Perkin's reaction

When benzaldehyde is heated with acetic anhydride in the presence of sodium acetate, condensation product is obtained which on hydrolysis give α, β- nsaturated acid (such as cinnamic acid) and the reaction is known as Perkin's reaction.

C6H5CHO Benzaldehyde+ H2CHCOOCOCH3acetic anhyride -H2OCH3COONa C6H5CH=CHCOOHCOHOCH3  -CH3COOHH2O/ C6H5CH=CHCOOH cinnamic acid(α,β- unsaturated acid)                                                             


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47.

Which of the following will not respond to iodoform test?

  • Ethyl alcohol

  • Propanol-2

  • Propanol-1

  • Ethanal


48.

Which of the following acids will have lowest value of pKa?

  • CH3CH2COOH

  • CH3CHBrCOOH

  • CH3CHFCOOH

  • FCH2CH2COOH


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49.

Which of the following does not contain chiral carbon atom?

  • Lactic acid

  • 2-chlorobutanoic acid

  • Tartaric acid

  • Succinic acid


50.

What will be the compound if two valencies of carbonyl group are satisfied by two alkyl groups?

  • Aldehyde

  • Ketone

  • Acid

  • Acidic anhydride


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