The first order integrated rate equation is from Chemistry JEE Y

Subject

Chemistry

Class

JEE Class 12

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 Multiple Choice QuestionsMultiple Choice Questions

21.

The IUPAC name of the following compound is

  • 3-ethyl-2-methylbutanal

  • 2, 3-dimethylpentanal

  • 2-ethyl-3-methylbutanal

  • 2-ethyl-3-methylbutan-3-al


22.

Oxidation potential of unimoles of calomel is

  • + 0.25 V

  • 0.00 V

  • + 0.287 V

  • -0.28 V


23.

1 C electricity deposits

  • 10.8 g of Ag

  • 96500 g of Ag

  • electrochemical equivalent of Ag

  • half of electrochemical equivalent of Ag


24.

Given, for Sn4+/ Sn2+, standard reductiona potential is 0.15 V and for Au3+/ Au, standard reduction potential is 1.5 V.

For the reaction,

3Sn2+ + 2Au3+ → 3Sn4+ + 2Au

the value of Ecell° is

  • +1.35

  • +2.55

  • -1.35

  • -2.55


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25.

The isotope tha causes skin disease is

  • I131

  • S35

  • P31

  • None of these


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26.

The first order integrated rate equation is

  • k = xt

  • k = 2.303t logaa - x

  • k = 1t  ln aa - x

  • k = 1txa(a - x)


C.

k = 1t  ln aa - x

For first order,

rate = d[R]dt = k[R]

or, d[R][R] = kdt    ...(i)

On integrating equation (i)

d[R][R] = kdt

ln[R] = -kt + C  ...(ii)

At t = 0, [R] = [R0]   (where, R = final concentration, i.e. a - x and R0 is the initial concentration, i.e. a)

ln [R0] = C

On putting the value of C in equation (ii). we get

ln[R] = -kt + ln[R0]

-kt    = ln[R] - ln[R0]

kt      = ln[R0] - ln[R]

or, k = 1t ln R0R

or, k = 1t ln aa - x


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27.

For nuclear fusion reactions, the fusion temperature is of the order of

  • 105 K

  • 103 K

  • 107 K

  • 100 K


28.

The units of rate constant for first order reaction are

  • mol L-1s-1

  • s-1

  • Lmol-1s-1

  • L2mol-2s-1


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29.

German silver does not contain

  • Sn

  • Cu

  • Zn

  • Ni


30.

Ratio of loss in solvent to gain in CaCl2 tube is

  • p°p

  • pp°

  • p° - pp°

  • p - p°p


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