Subject

Chemistry

Class

JEE Class 12

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 Multiple Choice QuestionsMultiple Choice Questions

31.

The most abundant noble gas in atmosphere is

  • neon

  • argon

  • xenon

  • krypton


32.

Average rate of reaction for the following reaction.

2SO2(g) + O2(g)  2SO3(g) is written as

  • [SO2]t

  • -[O2]t

  • 12[SO2]t

  • [SO3]t


33.

Select the correct statement for thermoplastic polymer.

  • It does not become soft on heating under pressure

  • It cannot be remoulded

  • It is either linear or branched chain polymer

  • It is a cross- linked polymer.


34.

Which of the following is not an analgesic?

  • Ofloxacin

  • Penicillin

  • Aminoglycosides

  • Paracetamol


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35.

Butylated hydroxy anisole is a/an

  • antioxidant

  • cleansing agent

  • disinfectant

  • antihistamine


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36.

The amine 'A' when treated with nitrous acid gives yellow oily substance. The amine A is

  • triethylamine

  • trimethylamine

  • aniline

  • methylphenylamine


D.

methylphenylamine

Secondary amines when treated with nitrous acid give yellow oily substance. So, amine 'A' is methylphenyl amine. Reaction of nitrous acid with aliphatic amines,

Liberation of N2 gas + alcohol formation

R-NH2 + HNO2 → R-N+≡NCl- H2O ROH + N2 + HCl

Reaction of nitrous acid with aromatic amines

Liberation of N2 gas + Phenol formation

PhNH2 + HNO2 + HCl 273 -278 K Ph-N≡NCl- → PhOH + HCl + N2

Reaction of nitrous acid with 2° amines: With HNO2, they give nitroso amines, which being insoluble in dilute acids separate as yellow oily compound.

R2NH + HONO → R2-N-N=O

N-nitroso dialkyl amine (yellow oil)

Reaction of nitrous acid with 3° amines : Aliphatic 3° amines on reaction with HONO formsoluble nitrite salts, while aromatic 3° amines form green coloured p -nitroso amines.

             

 


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37.

Bullet proof helmets are made from

  • lexan

  • saran

  • glyptal

  • thiokol


38.

lsopropyl methyl ether when treated with cold hydrogen iodide gives

  • isopropyl iodide and methyl iodide

  • isopropyl alcohol and methyl iodide

  • isopropyl alcohol and methyl alcohol

  • isopropyl iodide and methyl alcohol


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39.

Glucose on oxidation with bromine water yields gluconic acid. This reaction confirms the presence of

  • six carbon atoms linked in straight chain

  • secondary alcoholic group in glucose

  • aldehyde group in glucose

  • primary alcoholic group in glucose


40.

Select the compound which on treatment with nitrous acid liberates nitrogen.

  • Nitroethane

  • Triethylamine

  • Diethylamine

  • Ethylamine


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