Subject

Chemistry

Class

JEE Class 12

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 Multiple Choice QuestionsMultiple Choice Questions

31.

An element has a body centered cubic structure with a unit cell edge length of 400 pm. Atomic mass of an element is 24 g mol-1. What is the ·density of the element? (NA = 6 × 1023 mol-1)

  • 2.50 g cm-3

  • 1.80 g cm-3

  • 3.60 g cm-3

  • 1.25g cm-3


32.

Which one of the following is more reactive towards SN2 reaction ?

  • (CH3)3CX

  • (CH3)2CHX

  • CH3CH2X

  • CH3X


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33.

What are X and Y in the following reactions?


A.

(i) H2O is hlghly polar in nature and aniline is hlghly reactive towards electrophilic substitution,

Thus, Br2 in H2O gives 2, 4, 6 tribromo aniline as main product i.e

                               

(ii) On the other hand CH3COOH wll decrease the reactivity by replacing the H-atom of -NH2 group wth CH3CO-group to give

                                 

and as a result only mono-substituted bromine at p-position is the major product  i.e ,

                        


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34.

Which one of the following is not used as an initiator in ionic polymerisation?

  • NaNH2

  • SnCl2

  • AlCl3

  • (C6H5CO)2O2


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35.

What is Z in the followmg sequence of reactions?

 

  • —CO—CH3

  • —CO—Cl

  • —CH3

  • —CH2—CH3


36.

What are X and Y in the following reactions?

CH2O (ii) H3O+(i) X CH3(CH2)2CH2OHY (ii) H3O+(i) C2H5MgBr CH3CH2C(CH3)2OH

  • X Y
    CH3-CH(CH3)-MgBr C2H5COCH3
  • X Y
    CH3CH2CH2MgBr CH3-CO-CH3
  • X Y
    (CH3)3CMgBr CH3-CO-CH3
  • X Y
    CH3-CH2-MgBr CH3CH2CHO

37.

Which of the following structure represents the compound, generally added to soaps to impart antiseptic properties?


38.

The increasing order of acidity of the following carboxylic acids is

  I          II          III       IV

  • III < IV < II < I

  • II < III < II < I

  • I < II < IV < III

  • III < IV < I < II


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39.

Identify the statement which is not correct from the following.

(i)Carbohydrates are stored as glycogen in animals.

(ii) In glycylalanine, CO of peptide bond belongs to alanine.

(iii) Base - sugar- phosphate unit is known as nucleoside.

(iv) Obesity is due to hypothyroidism.

The correct answer is:

  • i, iv

  • ii, iii, iv

  • i, iii, iv

  • ii, iii


40.

The drug, which was designed to prevent the interaction of histamine with the receptors present in the stomach wall is

  • prontosil

  • cimetidine

  • aspartame

  • equanil


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