Which of the following are not state functions?I) q + WII) qIII)

Subject

Chemistry

Class

NEET Class 12

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 Multiple Choice QuestionsMultiple Choice Questions

1.

Equal volumes of three acid solutions of pH 3.4 and 5 are mixed in a vessel. What will be the H+ ion concentration in the mixture?

  • 1.11 x 10-4 M

  • 3.7 x 10-4 M 

  • 3.7 x 10-3 M

  • 3.7 x 10-3 M

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2.

The angular shape of ozone molecule (O3) consists of 

  • 1 sigma and 2 pi bonds

  • 2 sigma and 2 pi bonds

  • 1 sigma and 1 pi bonds

  • 1 sigma and 1 pi bonds

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3.

Which of the following are not state functions?
I) q + W
II) q
III) W
IV) H-TS

  • (I) and (IV)

  • (II) (III) and (IV)

  • (I), (II) and (III)

  • (I), (II) and (III)


D.

(I), (II) and (III)

A state function is the property of the system whose value depends only on the initial and final state of the system and is independent of the path.

Therefore, 

Internal energy (ΔE) = q +W
It is a state function because it is independent of the path. It is an extensive property.

∴ Gibbs energy (G) = H -TS

It is also a state function because it is independent of the path. It is also extensive property. 
Heat (q) and work (W) are not state functions being path dependent.

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4.

If uncertanity in position and momentum are equal, then uncertaninty in velocity is 

  • fraction numerator 1 over denominator 2 straight m end fraction square root of straight h over straight pi end root
  • square root of fraction numerator straight h over denominator 2 straight pi end fraction end root
  • 1 over straight m square root of h over pi end root
  • 1 over straight m square root of h over pi end root
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5.

The correct order of decreasing second ionisation enthalpy of Ti (22), V (23), Cr(24) and Mn (25) is 

  • Cr > Mn> V > Ti

  • V > Mn > Cr >Ti

  • Mn > Cr> Ti >V

  • Mn > Cr> Ti >V

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6.

If a gas expands at constant temperature, it indicates that

  • the kinetic energy of molecules decrease

  • the pressure of the gas increases

  • the kinetic energy of molecules remains the same

  • the kinetic energy of molecules remains the same

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7.

For the gas phase, reaction,

PCl5 (g) ⇌ PCl3 (g) Cl2 (g)
Which of the following conditions are correct?

  • Δ H = 0 and ΔS > 0

  • ΔH >0 and ΔS > 0

  • Δ H < 0 and ΔS < 0

  • Δ H < 0 and ΔS < 0

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8.

Number of moles of MnO4- required to oxidies one mole of ferrous oxalate completely in acidic medium will be 

  • 0.6 mole

  • 0.4 mole

  • 7.5 mole

  • 7.5 mole

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9.

If the concentration of OH- ions in the reaction Fe(OH)3 (s)  ⇌ Fe3+ (aq) + 3OH-(aq) is decreased by 1/4 times, then equilibrium concentration of Fe3+ will increase by 

  • 8 times

  • 16 times

  • 64 times

  • 64 times

1381 Views

10.

The sequence of ionic mobility in aqueous solution is 

  • K+ > Na+ > Rb+ > Cs+

  • Cs+ > Rb+ > K+ >Na+

  • Rb+ > K+> Cs+ > Na+

  • Rb+ > K+> Cs+ > Na+

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