In which of the following equilibrium Kc and Kp are not equal?
2NO (g) ⇌ N2 (g) + O2 (g)
SO2 (g) + NO2 (g) ⇌ SO3 (g) + NO (g)
H2 (g) + I2 (g) ⇌ 2 HI (g)
H2 (g) + I2 (g) ⇌ 2 HI (g)
Which one of the following ion has electronic configuration [Ar] 3d6?
(At. no: Mn = 25, Fe = 26, Co = 27, Ni = 28)
Ni3+
Mn
Fe3+
Fe3+
In a buffer solution containing an equal concentration of B- and HB, the Kb for B- is 10-10.The pH of buffer solution is
10
7
6
6
Liquid hydrocarbons can be converted to a mixture of gaseous hydrocarbons by
oxidation
cracking
distillation under reduced pressure
distillation under reduced pressure
The tendency of BF3, BCl3 and BBr3 to behave as Lewis acid decreases in the sequence
BCl3 > BF3 > BBr3
BBr3 > BCl2 > BF3
BBr3 > BF3 > BCl3
BBr3 > BF3 > BCl3
Property of the alkaline earth metals that increases with their atomic number
the solubility of their hydroxides in water
the solubility of their sulphates in water
ionisation energy
ionisation energy
A.
the solubility of their hydroxides in water
Electronegativity, as well as ionisation energy both, usually decrease on moving downward a group with an increase in atomic number. The hydroxides and sulphates of alkaline earth metals are ionic solids and the solubility of ionic solids is governed by two factors viz, lattice energy and hydration energy. For solubility hydration, energy > lattice energy.
Hydration energy varies inversely with size, ie, decreases with increase in size. However, lattice energy in case of sulphates, remains almost same with an increase in the atomic number of alkaline earth metals, due to the large size of sulphates ion. Hence, hydration energy only governs the solubility of alkaline earth metal sulphates decrease as the hydration energy decreases on moving downward the II A group.
Which of the following alkaline earth metal sulphates has hydration enthalpy higher than the lattice enthalpy?
CaSO4
BeSO4
BaSO4
BaSO4
For the reaction
the value of the rate of disappearance of N2O5 is given as
6.25 x 10-3 mol L-1s-1 and 6.25 x 10-3 mol L-1 s-1
1.25 x 10-2 mol L-1s-1 and 6.25 x 10-3 mol L-1 s-1
6.25 x 10-3 mol L-1s-1 and 3.125 x 10-3 mol L-1 s-1
6.25 x 10-3 mol L-1s-1 and 3.125 x 10-3 mol L-1 s-1