Subject

Chemistry

Class

NEET Class 12

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 Multiple Choice QuestionsMultiple Choice Questions

11.

In which of the following equilibrium Kc and Kp are not equal?

  • 2NO (g) ⇌ N2 (g)  + O2 (g)

  • SO2 (g) + NO2 (g) ⇌ SO3 (g) + NO (g)

  • H2 (g) + I2 (g) ⇌ 2 HI (g)

  • H2 (g) + I2 (g) ⇌ 2 HI (g)

971 Views

12.

Which one of the following ion has electronic configuration [Ar] 3d6?
(At. no:  Mn = 25, Fe = 26, Co = 27, Ni = 28)

  • Ni3+

  • Mn

  • Fe3+

  • Fe3+

561 Views

13.

In a buffer solution containing an equal concentration of B- and HB, the Kb for B- is 10-10.The pH of buffer solution is

  • 10

  • 7

  • 6

  • 6

1065 Views

14.

Liquid hydrocarbons can be converted to a mixture of gaseous hydrocarbons by

  • oxidation

  • cracking

  • distillation under reduced pressure

  • distillation under reduced pressure

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15.

The tendency of BF3, BCl3 and BBr3 to behave as Lewis acid decreases in the sequence

  • BCl3 > BF3 > BBr3

  • BBr3 > BCl2 > BF3

  • BBr3 > BF3 > BCl3

  • BBr3 > BF3 > BCl3

1888 Views

16.

Which one of the following molecular hydrides acts as a Lewis acid? 

  • NH3

  • H2O

  • B2H6

  • B2H6

920 Views

17.

In the following the most stable conformation of n-butane is

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18.

Property of the alkaline earth metals that increases with their atomic number

  • the solubility of their hydroxides in water

  • the solubility of their sulphates in water

  • ionisation energy 

  • ionisation energy 


A.

the solubility of their hydroxides in water

Electronegativity, as well as ionisation energy both, usually decrease on moving downward a group with an increase in atomic number. The hydroxides and sulphates of alkaline earth metals are ionic solids and the solubility of ionic solids is governed by two factors viz, lattice energy and hydration energy. For solubility hydration, energy > lattice energy.
Hydration energy varies inversely with size, ie, decreases with increase in size. However, lattice energy in case of sulphates, remains almost same with an increase in the atomic number of alkaline earth metals, due to the large size of sulphates ion. Hence, hydration energy only governs the solubility of alkaline earth metal sulphates decrease as the hydration energy decreases on moving downward the II A group.

On the other hand, in the case of hydroxides, the lattice energies are different because of medium size of hydroxide ions and decreases on moving from Be to Ba. This tends to increase the solubility and to overcome the counter-effect produced by the decrease in hydration energy. Hence, the solubility of alkaline earth metal hydroxides increases with increase in the atomic number of alkaline earth metals.
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19.

Which of the following alkaline earth metal sulphates has hydration enthalpy higher than the lattice enthalpy? 

  • CaSO4

  • BeSO4

  • BaSO4

  • BaSO4

410 Views

20.

For the reaction

straight N subscript 2 straight O subscript 5 left parenthesis straight g right parenthesis thin space rightwards arrow space 2 NO subscript 2 space left parenthesis straight g right parenthesis thin space plus space 1 half space straight O subscript 2 space left parenthesis straight g right parenthesis
the value of the rate of disappearance of N2O5 is given as 

  • 6.25 x 10-3 mol L-1s-1 and 6.25 x 10-3 mol L-1 s-1

  • 1.25 x 10-2 mol L-1s-1 and 6.25 x 10-3 mol L-1 s-1

  • 6.25 x 10-3 mol L-1s-1 and 3.125 x 10-3 mol L-1 s-1

  • 6.25 x 10-3 mol L-1s-1 and 3.125 x 10-3 mol L-1 s-1

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