Multiple Choice QuestionsOxidation states of P in H4P2O5, H4P2O6, H4P2O7, are respectively
+3, +5, +4
+5, +3, +4
+5, +4,+3
+5, +4,+3
The correct order of increasing bond angles in
Cl2O < ClO2 < ClO2-
ClO2 <Cl2O< ClO2-
Cl2O < ClO2- < ClO2
Cl2O < ClO2- < ClO2
25.3 g of sodium carbonate, Na2CO3 is dissolved in enough water to make 250 mL of solution. If sodium carbonate dissociates completely molar concentration of sodium ion, Na+ and carbonate ion, CO32- are respectively (Molar mass of Na2CO3 = 106 g mol-1)
0.955 M and 1.910 M
1.910 M and 0.955 M
1.90 M and 1.910 M
1.90 M and 1.910 M
The existence of two different coloured complexes with the composition of [Co(NH3)4Cl2]+ is due to
linkage isomerism
geometrical isomerism
Coordination isomerism
Coordination isomerism
During the kinetic study of the reaction, 2A + B --> C+ D, following results were obtained
|
|
[A]/mol L- |
[B]/ mol L- |
Initial rate of formation of D/ mol L- min- |
|
I |
0.1 |
0.1 |
6.0 x 10-3 |
|
II |
0.3 |
0.2 |
7.2 x 10-2 |
|
III |
0.3 |
0.4 |
2.88 x 10-1 |
|
IV |
0.4 |
0.1 |
2.40 x10-2 |
rate = k[A]2[B]
rate = k [A][B]
rate = k[A]2[B]2
rate = k[A]2[B]2
Which one of the following species does not exist under normal conditions?
(+)Sucrose
(+)Lactose
(+) Maltose
(+) Maltose
Given are cyclohexanol (I), acetic acid (II), 2,4,6-trinitropenol (III) and phenol (IV). In these, the order of decreasing acidic character will be
III > II> IV> I
II > III> I > IV
II > III> IV> I
II > III> IV> I
A.
III > II> IV> I
Higher the tendency to give a proton, higher is the acidic character, and tendency to lose a proton depends upon the stability of intermediate, ie, carbanion formed.
2,4,6 - trinitrophenol after the loss of a proton gives 2,4,6 -trinitrophenoxide ion which is stabilised by resonance -I effect and -M effect thus a most acidic among the given compounds. Phenol after losing a proton form phenoxide ion which is also stabilised by resonance, -M and -I effects but is less stabilised as compared to 2,4,6 trinitrophenoxide ions. Thus, it is less acidic as compared to 2,4,6 trinitrophenol. (CH3COOH) after losing a proton give acetate CH3OO- ion which is stabilised by only resonance. However, it is more resonance stabilised as compared to a phenoxide ion, thus more acidic as compared to phenol. 2,4,6 tri-nitrophenol, however, is more acidic than acetic acid due to the presence of three electron withdrawing - NO2 groups. cyclohexanol gives an anion that is least stable among the given, thus, it is least acidic.
Hence, the correct order of acidic strength is 2,4,6 -trinitrophenol > acetic acid > phenol > cyclohexanol
III> II> IV> I
Which one is most reactive towards SN1 reaction?
C6H5CH(C6H5)Br
C6H5CH(CH3)Br
C6H5C(CH3)(C6H5)Br
C6H5C(CH3)(C6H5)Br
Which one of the following is employed asa tranquilizer drug?
Promethazine
Valium
Naproxen
Naproxen
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