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(a) Draw the structures of all isomeric alcohols of molecular formula C5H12O and give their IUPAC names.
(b) Classify the isomers of alcohols in the above part of question as primary, secondary and tertiary alcohols.   


(a) Eight isomeric alcohols are possible:


b)  Primary alcohol: pentan-1-ol; methylbutan-1-ol; 3-methyl-1-ol; 2,2Dimethylpropan-1-ol.

Secondary alcohol: Pentan-2-ol; 3-methylbutan-2-ol; pentan-3-ol

Tertiary alcohol: 2-methylbutan-2-ol

 
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What is meant by hydroboration-oxidation reaction? Illustrate it with an example.

The addition of borane followed by oxidation is known as the hydroboration-oxidation reaction.

In the first step, alkene reacts with diborane (B2H6) as boron hydride (BH3) to form an alkyl borane. In the next step, the alkyl borane is oxidised by alkaline H2O2 to form an alcohol. The indirect hydration proceeds according to Anti Markovnikoff’s rule. For example,


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Write structures of the compounds whose IUPAC names are as follows:
Cyclopent-3-en-1-ol

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Write structures of the compounds whose IUPAC names are as follows:
3-Cyclohexylpentan-3-ol

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Write structures of the compounds whose IUPAC names are as follows:
3-Chloro methyl pentan-1-ol

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