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The Solid State

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Chemistry I

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Chemistry

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CBSE Gujarat Board Haryana Board

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Class 10 Class 12
what is Frenkel defect.Why is Frenkel defect found in AgCl ?

Frenkel Defect: This defect is shown by ionic solids. The smaller ion (usually cation) is dislocated from its normal site to an interstitial site . It creates a vacancy defect at its original site and an interstitial defect at its new location.
 Frenkel defect is shown by ionic substance in which there is a large difference in the size of ions so it is due to difference in size of Ag
+ and CI, Ag+ occupies voids.

Refractive index of a solid is observed to have the same value along all directions. Comment on the nature of this solid. Would it show clevage property?

Refractive index of a solid which have the same value along all directions are isotropic in nature. It would not show cleavage property.

Classify the following as amorphous or crystalline solids: Polyurethane, naphthalene, benzoic acid, teflon, potassium nitrate, cellophane, polyvinyl chloride, fibre glass, copper.

Amorphous solids: Polyurethane, teflon, cellophane, polyvinyal chloride, fibre glass.
Crystalline solids: naphthlene, benzoic acid, potassium nitrate, copper.

Why is glass considred a super-cooled liquid?

Glass is amorphous solids and  have a tendency to flow, though very slowly. Therefore, these are called pseudo solids or super cooled liquids .

Why are solids rigid?

Solids are rigid because the internuclear distance between the  molecules of a solid are very less and closely packed and their positions are fixed due to the strong forces of attraction between them.

Why do solids have a definite volume?

A solid have a definite volume because the inter molecular distance  between its molecules are fixed.