Subject

Chemistry

Class

CBSE Class 12

Pre Boards

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Sample Papers

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 Multiple Choice QuestionsShort Answer Type

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21.

Write one difference in each of the following :
Homogeneous catalysis and Heterogeneous catalysis


Homogeneous catalysis: When the reactants and the catalyst are in same phase (i.e., Liquid or gas), the process is said to be homogeneous catalysis. For example, Oxidation of sulphur dioxide into sulphur trioxide with dioxygen in presence of oxides of nitrogen as the catalyst in the process.
2SO2(g) + O2(g)→ NO(g) +2SO3(g)

Heterogeneous catalysis: The catalytic process in which the reactant and the catalyst are in different phase is known as heterogeneous.For example Oxidation of sulphur dioxide into sulphur trioxide in the presence of Pt.
2SO2(g) + pt(s)→ 2SO3 (g)

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22.

Following data are obtained for the reaction :
N2O5 → 2NO2 + ½O2

t/s 0 300 600
[N2O5]/mol L–1 1.6 × 10–2 0.8 × 10–2 0.4 × 10–2

(a) Show that it follows first order reaction.
(b) Calculate the half-life.
(Given log 2 = 0.3010 log 4 = 0.6021)

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23.

Write the principle of the method used for the refining of germanium.

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24.

Out of PbS and PbCO3 (ores of lead), which one is concentrated by froth flotation process preferably?

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25.
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26.

Give reasons:
Thermal stability decreases from H2O to H2Te.

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27.

Give reasons:
Fluoride ion has higher hydration enthalpy than chloride ion.

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28.

Give reasons:
Nitrogen does not form pentahalide.

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29.

Account for the following :
Transition metals form large number of complex compounds.

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30.

Account for the following :
The lowest oxide of transition metal is basic whereas the highest oxide is
amphoteric or acidic.

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