Subject

Chemistry

Class

JEE Class 12

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 Multiple Choice QuestionsMultiple Choice Questions

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11.

The ground state magnetic property of B2 and C2 molecules will be

  • B2 paramagnetic and C2 diamagnetic

  • B2 diamagnetic and C2 paramagnetic

  • Both are diamagnetic

  • Both are paramagnetic


A.

B2 paramagnetic and C2 diamagnetic

According to molecular orbital theory, outer configuration for 

[C2] = C12 → πpx2 = πy2

Thus, it is diamgentic in nature.

[B2] = B10 - > πx1 = πpy1

Thus, it is paramagnetic in nature.


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12.

Which of the following atoms should have the highest Ist electron affinity?

  • F

  • O

  • N

  • C


13.

PbCl2 is insoluble in cold water. Addition of HCl increases its solubility due to

  • formation of soluble complex anions like [PbCl3]-

  • oxidation of Pb(II) to PB(IV)

  • formation of [Pb(H2O)6]2+

  • formation of polymeric lead complexes


14.

Of the following compounds, which one is the strongest Bronsted acid in a aqueous solution?

  • HClO3

  • HClO2

  • HOCl

  • HOBr


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15.

The yield of acetanilide in the reaction (100% conversion) of 2 moles of aniline with 1 mole of acetic anhydride is

  • 270 gm

  • 135 gm

  • 67.5 gm

  • 177 gm


16.

You are supplied with 500 mL each of 2N HCl and SN HCL What is the maximum volume of 3M HCl that you can prepare using only these two solutions?

  • 250 mL

  • 500 mL

  • 750 mL

  • 1000 mL


17.

Which one of the following corresponds to a photon of highest energy?

  • λ = 300 mm

  • v = 3 × 108 s-1

  • v = 30 cm-1

  • ε = 6.626 × 10-27 J


18.

Equilibrium constants for the following reactions at 1200 K are given

2H2O (g)  2H2 (g) + O2 (g)    [K1 = 6.8 × 10-8]

2CO2 (g)  2CO (g) + O2 (g)    [K2 = 1.6 × 10-6]

The equilibrium constant for the reaction?

H2(g) + CO2(g)  CO (g) + H2O (g)

at 1200 K will be

  • 0.05

  • 20

  • 0.2

  • 5.0


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19.

Which of the following solutions will turn violet when a drop of lime juice is added to it?

  • A solution of NaI

  • A solution mixture of KI and NaIO3

  • A solution mixture of NaI and KI

  • A solution mixture of KIO3 and NaIO3


20.

What will be the normality of the salt solution obtained by neutralising x mL y (N) HCl with y mL x(N) NaOH, and finally adding (x + y) mL distilled water

  • 2(x + y)xy N

  • xy2(x + y)N

  • 2xyx + y N

  • x + yxyN


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