Discuss the preparation of aldehydes and ketones from alkenes.

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 Multiple Choice QuestionsShort Answer Type

181. The boiling points of carbonyl compounds are higher than the non-polar alkanes but lower than that of alcohols of comparable molecular mass. Give reasons.
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182. How will you obtain aldehydes from primary alcohols?
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183. How will you prepare ketones from alcohols?
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184. Discuss the method of preparation of an aldehyde from acid chloride.
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 Multiple Choice QuestionsLong Answer Type

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185. Discuss the preparation of aldehydes and ketones from alkenes.


Preparation of aldehydes:

From acyl chloride (acid chloride):
Acyl chloride is hydrogenated over catalyst, palladium on barium sulphate. This reaction is called Rosenmund reduction.



From nitriles and esters:

Nitriles are reduced to corresponding  imine with stannous chloride in the presence of hydrochloric acid which on hydrolysis give corresponding aldehyde.



Preparation of ketones:

Treatment of acyl chlorides with dialkylcadmium gives ketone.



From benzene or substituted benzenes:

when benzene or substituted benzene is treated with acid chloride in the presece of anhydrous aluminium chloride, it afford the corresponding keton. This reaction is known as Friedel - crafts acylation reaction.



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186. How will you obtain acetophenone from (i) benzene (ii) ethyl benzene (iii) benzoyl chloride?
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 Multiple Choice QuestionsShort Answer Type

187. Name the following compounds according to IUPAC system of nomenclature:
CH3CH(CH3)CH2CH2CHO
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188. Name the following compounds according to IUPAC system of nomenclature:
CH3CH2COCH(C2H5)CH2CH2Cl
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189. Name the following compounds according to IUPAC system of nomenclature:
CH3CH = CHCHO
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190. Name the following compounds according to IUPAC system of nomenclature:
CH3COCH2COCH3
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