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 Multiple Choice QuestionsMultiple Choice Questions

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21.

Which statement is not correct for ortho and para hydrogen?

  • They have different boiling points

  • Ortho-form is more stable than para-form

  • They differ in their nuclear spin

  • The ratio of ortho to para hydrogen changes with change in temperature


22.

In the IUPAC system, PhCH2CH2CO2H is named as

  • 3-phenylpropanoic acid

  • benzylacetic acid

  • carboxyethylbenzene

  • 2-phenylpropanoic acid


23.

The correct order of acid strengths of benzoic acid (X), peroxybenzoic acid (Y) and p-nitrobenzoic acid (Z) is

  • Y > Z > X

  • Z > Y > X

  • Z > X > Y

  • Y > X > Z


24.

The structure of the product P of the following reaction is


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25.

Choose the correct statement(s) among the following.

  • CH3CHO on reaction with HCN gives racemic mixture 

  • CH3-CH=NOH shows geometrical isomerism


26.

Optical isomerism is exhibited by (ox= oxalate anion; en= ethylenediamine).

  • cis-[CrCl2(ox)2]3-

  • [Co(en)3]3+

  • trans-[CrCl2(ox)2]3-

  • [Co(ox)(en)2]+


27.

In a mixture, two enantiomers are found to be present in 85% and 15% respectively. The enantiomeric excess (ee) is

  • 85%

  • 15%

  • 70%

  • 60%


28.

Among the following structures the one which is not a resonating structure of others is

            

  • I

  • II

  • III

  • IV


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29.

In the Lassaigne's test for the detection of nitrogen in an organic compound, the appearance of blue coloured compound is due to

  • ferric ferricyanide

  • ferrous ferricyanide

  • ferric ferrocyanide

  • ferrous ferrocyanide


30.

The IUPAC name of the compound X is

  • 4-cyano-4-methyl-2-oxopentane

  • 2-cyano-2-methyl- 4-oxopentane

  • 2, 2-dimethyl-4-oxopentanenitrile

  • 4-cyano-4-methyl-2-pentanone


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