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21.

At a certain temperature the time-required for the complete diffusion of 200 mL of H2 gas is 30 min. The time required for the complete diffusion of 50 mL of O2 gas at the same temperature will be

  • 60min

  • 30min

  • 45min

  • 15min


22.

The RMS velocity of CO gas molecules at 27°C is approximately 1000 m/s. For N2 molecules at 600 K, the RMS velocity is approximately

  • 2000 m/s

  • 1414 m/s

  • 1000 m/s

  • 1500 m/s


23.

A gas can be liquefied at temperature T and pressure p provided.

  • T = Tc and p < pc

  • T < Tc and p > pc

  • T > Tc and p > pc

  • T > Tc and p < pc


24.

The dispersed phase and dispersion medium of fog respectively are

  • solid, liquid

  • liquid, liquid

  • liquid, gas

  • gas, liquid


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25.

For the reaction,
2SO(g) + O2 (g) → 2SO3 (g) at 300 K, the value of G° is -690.9 R. The equilibrium constant value for the reaction at that temperature is (R is gas constant)

  • 10 atm-1

  • 10 atm

  • 10

  • 1


26.

Four gases P, Q. R and S have almost same values of 'b' but their 'a' values (a, b are van der Waals' constants) are in the order Q < R < S < P. At a particular temperature, among the four gases, the most easily liquefiable one is

  • P

  • Q

  • R

  • S


27.

The units of surface tension and viscosity of liquids respectively are

  • kg m-1s-1, Nm-1

  • kg s-2, kg m-1s-1

  • Nm-1, kg m-1s-2

  • kg s-1, kg m-2s-1


28.

The compound that will have a permanent dipole moment among the following is

           

  • I

  • II

  • III

  • IV


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29.

The compressibility factor (Z) of one mole of a van der Waals' gas of negligible 'a' value is

  • 1

  • bpRT

  • 1+bpRT

  • 1-bpRT


30.

A van der Waals' gas may behave ideally when

  • the volume is very low

  • the temperature is very high

  • the pressure is very low

  • the temperature, pressure and volume all are very high


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