Phosphorus pentachloride dissociates as follows, in a closed reaction vessel,
PCl5 (g) ⇌ PCl3(g) + cl2(g)
If total pressure at equilibrium of the reaction mixture is P and degree of dissociation of PCl5 is x, the partial pressure of PCl3 will be
The formation of the oxide ion O2-(g) requires first an exothermic and then an endothermic step as shown below
Oxygen is more electronegative
O- ion has comparatively larger size than oxygen atom
O- ion will tend to resist the addition of another electron
O- ion will tend to resist the addition of another electron
As the temperature is raised from 20°C to 40°C, the average kinetic energy of neon atoms changes by a factor of which of the following?
1/2
2
313/293
313/293
In Vander Waals equation of state of the gas law, the constant ‘b’ is a measure of
intermolecular repulsions
intermolecular collisions per unit volume
Volume occupied by the molecules
Volume occupied by the molecules
An ideal gas expands in volume from 1×10-3 m3 to 1×10-2 m3 at 300 K against a constant pressure of 1×105 Nm-2. The work done is
-900 J
900 J
2780 J
2780 J
Which of the following has the dimension if [ML0T-2]?
Coefficient of viscosity
Surface tension
Vapour pressure
Kinetic energy
The boiling points of HF, HCl, HBr and HI follow the order
HF> HCl > HBr > HI
HF> HI> HBr > HCl
HI> HBr > HCl> H
HCl > HF> HBr > HI
At a certain temperature, the value of the slope of the plot of osmotic pressure () against concentration (C in molL-1) of a certain polymer solution is 291R. The temperature at which osmotic pressure is measured, is (R is gas constant)
271°C
18°C
564 K
18 K
For one mole of an ideal gas, the slope of V vs. T curve at constant pressure of 2 atm is X L mol-1 K-1.The value of the ideal universal gas constant 'R' in terms of X is
X L atm mol-1 K-1
x/2 L atm mol-1 K-1
2X L atm mol-1 K-1
2X atm L-1 mol-1 K-1
At a certain temperature the time-required for the complete diffusion of 200 mL of H2 gas is 30 min. The time required for the complete diffusion of 50 mL of O2 gas at the same temperature will be
60min
30min
45min
15min