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21.

The RMS velocity of CO gas molecules at 27°C is approximately 1000 m/s. For N2 molecules at 600 K, the RMS velocity is approximately

  • 2000 m/s

  • 1414 m/s

  • 1000 m/s

  • 1500 m/s


22.

A gas can be liquefied at temperature T and pressure p provided.

  • T = Tc and p < pc

  • T < Tc and p > pc

  • T > Tc and p > pc

  • T > Tc and p < pc


23.

The dispersed phase and dispersion medium of fog respectively are

  • solid, liquid

  • liquid, liquid

  • liquid, gas

  • gas, liquid


24.

For the reaction,
2SO(g) + O2 (g) → 2SO3 (g) at 300 K, the value of G° is -690.9 R. The equilibrium constant value for the reaction at that temperature is (R is gas constant)

  • 10 atm-1

  • 10 atm

  • 10

  • 1


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25.

Four gases P, Q. R and S have almost same values of 'b' but their 'a' values (a, b are van der Waals' constants) are in the order Q < R < S < P. At a particular temperature, among the four gases, the most easily liquefiable one is

  • P

  • Q

  • R

  • S


26.

The units of surface tension and viscosity of liquids respectively are

  • kg m-1s-1, Nm-1

  • kg s-2, kg m-1s-1

  • Nm-1, kg m-1s-2

  • kg s-1, kg m-2s-1


27.

The compound that will have a permanent dipole moment among the following is

           

  • I

  • II

  • III

  • IV


28.

The compressibility factor (Z) of one mole of a van der Waals' gas of negligible 'a' value is

  • 1

  • bpRT

  • 1+bpRT

  • 1-bpRT


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29.

A van der Waals' gas may behave ideally when

  • the volume is very low

  • the temperature is very high

  • the pressure is very low

  • the temperature, pressure and volume all are very high


30.

Mixing of two different ideal gases under isothermal reversible condition will lead to

  • increase of Gibbs free energy of the system

  • no change of entropy of the system

  • increase of entropy of the system

  • increase of enthalpy of the system


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