Which of the following compounds can be used as antifreeze in automobile radiators?
Methyl alcohol
Glycol
Nitrophenol
Nitrophenol
The reaction of phenol with chloroform in the presence of dilute sodium hydroxide finally introduces, which one of the following functional group?
-CH2Cl
-COOH
-CHCl2
-CHCl2
Given are cyclohexanol (I), acetic acid (II), 2,4,6-trinitropenol (III) and phenol (IV). In these, the order of decreasing acidic character will be
III > II> IV> I
II > III> I > IV
II > III> IV> I
II > III> IV> I
Among the following four compounds
A) Phenol
B) Methyl Phenol
C) meta - nitrophenol
D) para-nitrophenol
the acidity order is
D > C > A > B
C > D > A> B
A > D > C > B
A > D > C > B
A.
D > C > A > B
An electron withdrawing group (-I showing group like -NO2, -CN) stabilises the phenoxide ion, thus when present, increases the acidity of phenol. On the other hand, the electron releasing groups (+I showing group like -CH3, -C2H5), when present, decrease the acidity of phenol by destabilising phenoxide ion. Hence, the correct order of acidity of given compound is
p-nitrophenol > m-nitrophenol > phenol > methyl phenol
Consider the following reaction,
the product,Z,is
toluene
benzaldehyde
benzoic acid
benzoic acid