Short Answer TypeArrange the following compounds in an increasing order of their solubility in water:
C6H5NH2, (C2H5)2NH, C2H5NH2Explain the following giving one example for each:
(i) Reimer-Tiemann reaction.
(ii) Friedel Craft’s acetylation of anisole.
How would you obtain
(i) Picric acid (2, 4, 6-trinitrophenol) from phenol,
(ii) 2-Methylpropene from 2-methylpropanol?
What is essentially the difference between α-form of glucose and β-form of glucose? Explain.
Explain why an alkylamine is more basic than ammonia.
(a) The basicity of amines depends on the +I effect of the alkyl groups. With increase in alkyl group the +I effect will increase which will increase the ease of donation of lone pair electron. Amine will accept a proton and from cation will be stabilized in water by salvation (by hydrogen bonding).better the salvation by hydrogen bonding higher will be the basic strength.
Hence, alkyl amine is more basic than ammonia
CH3NH2 > NH3
Long Answer Type(a) Differentiate between molarity and molality for a solution. How does a change in temperature influence their values?
(b) Calculate the freezing point of an aqueous solution containing 10.50 g of MgBr2in 200 g of water. (Molar mass of MgBr2 = 184 g) (Kf for water = 1.86 K kg mol-1)
Switch
