(a) Define molar conductivity of a solution and explain how molar conductivity changes with a change in concentration of solution for a weak and a strong electrolyte.
(b) The resistance of a conductivity cell containing 0.001 M KCl solution at 298 K is Ω 1500 . What is the cell constant if the conductivity of 0.001 M KCl solution at 298 K is 0.146x10-3 S cm-1?
(a) Complete the following chemical reactions equations:
(i) P4+SO2Cl2 -->
(ii) XeF6+H2O -->
(b) Predict the shape and the asked angle (90° or more or less) in each of the following cases:
(i) and the angle O - S - O
(ii) ClF3 and the angle F - Cl - F
(iii) XeF2 and the angle F - Xe - F
Complete the following chemical equations:
(i) NaOH+Cl2 -->
(ii) XeF4+O2F2--->
(b) Draw the structures of the following molecules:
(i) H3PO2
(ii) H2S2O7
(iii) XeOF4
Arrange the following compounds in an increasing order of their reactivity in nucleophilic addition reactions: ethanol, propanal, propanone, butanone.
Write any two reactions of glucose which cannot be explained by the open chain structure of glucose molecule.
The following two reactions of glucose cannot be explained by the open chain structure of glucose.
(i) Despite having the aldehyde group glucose does not give 2, 4-DNP test, Schiff’s test and it does not form the hydrogen sulphite addition product with NaHSO3.
(ii) The pentaacetate of glucose does not react with hydroxylamine indicating the absence of free- CHO group.
Draw the structure of the monomer for each of the following polymers:
(i) Nylon 6
(ii) Polypropene