Subject

Chemistry

Class

NEET Class 12

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 Multiple Choice QuestionsLong Answer Type

41.

In 'x' mL 0.3 N HCl, the addition of 200 mL distilled water or addition of 100 mL 0.1 N NaOH, gives the same final acid strength. Determine 'x'.


42.

Compound A treated with NaNH2 followed by CH3CH2Br gave compound B. Partial hydrogenation of compound B produced compound C, which on ozonolysis gave a carbonyl compound D, (C2H5O). Compound D did not respond to the iodoform test with I2/KI and NaOH. Find out the structures of A, B, C and D.


43.

The bacterial growth follows the rate law, dN/dt = kN where k is a constant and 'N' is the number of bacteria cell at any time. If the population of bacteria (number of cell) is doubled in 5 min find the time in which the population will be eight times of the initial one?


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44.

An organic compound with molecular formula C9H10O forms 2, 4-DNP derivative, reduces Tollen's reagent and undergoes Cannizaro reaction. On vigorous oxidation, it gives a dicarboxylic acid which is used in the preparation of terylene. Identify the organic compound.


The positive Brady's test (i.e., reaction with 2, 4-dinitrophenylhydrazine) indicates that the organic compound is carbonyl compound and Tollen's and Cannizaro reactions indicate that it is an aldehyde without α-hydrogen atom. As the end product is terephthalic acid, the compound must be p-ethyl benzaldehyde.


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45.

Deep blue CuSO4.5H2O is converted to a bluish-white salt at 100oC. At 250oC and 750oC it is then transformed to white powder and black material respectively. Identify the salts.


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