A metal has a fcc lattice. The edge length of the unit cell is 404 pm. The density of the metal is 2.72 g cm3. The molar mass of the metal is (NA vogadro's constant = 6.02x 1023 mol-1).
40 g mol-1
30 g mol-1
27g mol-1
20 g mol-1
A magnetic moment of 1.73 BM will be shown by one among the following
[Cu(NH3)4]2+
[Ni(CN)4]2-
TiCl4
[CoCl6]4-
A.
[Cu(NH3)4]2+
Magnetic moment, is related with number of unpaired electrons as
On solving n =1
Thus, the complex/compound having one unpaired electron exhibit a magnetic moment of 1.73 BM.
(a) In [Cu(NH3)4]2+
Cu2+ = [Ar] 3d9
(Although in the presence of strong field ligand NH3, the unpaired electron gets excited to higher energy level but it still remains unpaired).
(b) In [Ni(CN)4]2-
Ni2+= [Ar]3d8
But CN- being strong field ligand pair up the unpaired electrons and hence in this complex, number of unpaired electrons = 0.
(c) In [TiCl4]
Ti4+= [Ar] 3d7
(d) In [CoCl6]4-
Co2+ = [Ar] 3d7
It contains three unpaired electrons.
Thus, [Cu(NH3)4]2+ is the complex that exhibits a magnetic moment 1.73 BM.
Roasting of sulphides gives the gas X as a by-product. This is a colourless gas with choking smell of burnt sulphur. and causes great damage to respiratory organs as a result of acid rain. Its aqueous solution is acidic acts as a reducing agent and its acid has never been insolated. The gas X is
H2S
SO2
CO2
SO3
Which ofthe following lanthanoid ions is diamagnetic?
(At. nos. Ce = 58, Sm = 62, Eu = 63, Yb= 70)
Ce2+
Sm2+
Eu2+
Yb2+
Structure of the compound whose IUPAC name is 3-ethyl-2-hydroxy-4-methylhex-3-en-5-ynoic acid is
Antiseptics and disinfectants either kill or prevent growth of microorganisms. Identify which of the following is not true.
A 0.2% solution of phenol is an antiseptic while 1% solution acts as a disinfectant.
Chlorine and iodine are used as strong disinfectants.
Dilute solutions of boric acid and hydrogen, peroxide are strong antiseptics.
Disinfectants harm the living tissues.